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Nyzul Isle Investigation is another one of those events where team setups are very, very picky. Personally, the best teams I've gone with so far are;

RDM/WHM + PUP/WAR + RDM/WHM + PLD/NIN + THF/NIN + SAM/WAR(I had this as a group on 16-20. We cleared boss with one minute remaining. A win, but really crunched on time).

RDM/WHM + DRG/WHM + SAM/WAR + MNK/DNC + SAM/WAR + WHM/SCH. Cleared easy, 5-10 mins remaining.

A lot of Nyzul Isle success is simply luck. It all depends on the floors you get. Sometimes Eliminate All Enemies floors will take 10 mins, and after that, you are boned unless you get really easy floors after that.

I've seen PLD/NIN do great in Nyzul Isle(never gone with a PLD/WAR, though). However, the PLD/NIN was insanely geared, as were the other members of the group. Gear makes a difference, for all jobs attending.

However, in order to go PLD to Nyzul Isle, you will mostly have to make your own static. I suggest something along the lines of RDM, PLD, SAM, DRG, WHM/SCH + BRD(BRD can be replaced with a Damage Dealer). If you're gonna go PLD though, I'd suggest RDM + WHM/SCH as healers, and get DD jobs as the rest of the PT. Jobs like BST and DRG can go /WHM and still do great damage, while helping with heals as needed, if needed.

In all likely-hood, you won't be able to get a Nyzul PT via /sh - unless you're making it. Even then you'll probably still get "lol" remarks from people, because the majority of the idiots on FFXI are extremely brainwashed.